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How to Configure Email in Outlook 2016 Step #1 Adding or Modifying an Email Account A. To start setting up a new email account, go to the “File” tab and select “Add Account.” B. If you need to adjust the settings on an account that’s already set up in Outlook, choose “Account Settings,” then click “Change settings for this account or set up more connections.” Be cautious when changing an account’s connection type or removing